Ammonium thiocyanate – a new coolant in vapour-compression cooling?

https://www.nature.com/articles/s41586-025-10013-1

https://en.people.cn/n3/2026/0122/c90000-20417412.html

https://www.cas.cn/cm/202601/t20260123_5097040.shtml

Refrigeration technology through vapor-compression cooling contributes to about 2 percent of China’s GDP, but also consumes nearly 20 percent of its electricity and generates 7.8 percent of its carbon emissions.

As a potential new concept, the group of LI Bing at the CAS Institute of Metal Research discovered the dissolution barocaloric effect in an NH4 SCN salt solution. When pressure is applied to such a solution, solid NH SCN precipitates and releases heat. In the event of depressurization, the salt rapidly dissolves in the solution while absorbing a large amount of heat. At room temperature, the solution’s temperature can drop by nearly 30 degrees Celsius within 20 seconds, with even greater cooling performance achieved at higher temperatures, far surpassing the capabilities of current solid-state caloric materials. Simulations showed that a single cycle of this system can achieve 67 joules of heat absorption per gram of solution, with an energy efficiency as high as 77 percent, demonstrating significant potential for engineering and commercial applications.

The “dissolution-pressure effect” is analogous to squeezing a wet sponge soaked in salt water—the salt water is squeezed out and releases heat, and when the hand is released, the sponge reabsorbs the salt water. This process powerfully and rapidly absorbs a large amount of heat from the surroundings.

This new method unifies the refrigerant and heat-transfer mediums into a single fluid, achieving low carbon emissions, high cooling capacity and high heat transfer efficiency all at once.

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